Database/Fragrance/Methyl Ionones
Route-dependent · ISO 16128

Is Methyl Ionones natural?

It depends. Citral skeleton (C10) from Litsea cubeba oil or pine terpenes is natural, but from isobutylene and formaldehyde is petrochemical; the butanone carbons are always petrochemical.

INCI nameMethyl Ionones
CAS79-89-0
FormulaC14H22O · 206.32 Da
FunctionFragrance
FeedstockDominant route: synthetic citral (from isobutylene and formaldehyde)…

Why the score varies

This ingredient is made commercially by more than one route, and ISO 16128 scores the feedstock actually used. Without a supplier certificate of origin the value cannot be claimed.

RouteFeedstockNOIShareNotes
Synthetic citral + 2-butanone, acid cyclisationisobutylene, formaldehyde and butene-derived 2-butanone (petrochemical)0.00~80%
Natural-origin citral + 2-butanone, acid cyclisationLitsea cubeba oil or pine-terpene citral with petrochemical 2-butanone0.66~20%
Ask your supplier. A batch-specific certificate of origin or bio-based carbon test (ASTM D6866) settles which route applies.

How we scored it

C14H22O 206.3: citral-derived C10H16 136.2 + butanone-derived C4H6O 70.1 (petrochemical). Citral from essential oil or pine: 136.2/206.3 = 0.66; synthetic citral: 0.0.
What counts. ISO 16128-2 scores the atoms that remain in the final ingredient. Reagents, solvents, catalysts and protecting groups used during manufacture leave no mass behind and are not counted.

Where it comes from

Dominant route: synthetic citral (from isobutylene and formaldehyde) is condensed with petrochemical 2-butanone and cyclised with acid, giving 0.0. Alternative: citral from Litsea cubeba oil or pine terpenes goes through the same steps, giving 0.66.

In plain English

Violet- and woody-smelling fragrance materials made by joining citral with butanone and closing a ring with acid. They add a powdery floral note to perfumes. The citral can come from essential oils such as Litsea cubeba or be made from petrochemicals.

CosIng definition: Methyl Ionones is a mixture of isomers consisting of Alpha-Isomethyl Ionone, beta-isomethylionone, alpha-methylionone, and beta-methylionone

Natural alternatives with the same function

Structure

2D structure of Methyl Ionones

3-methyl-4-(2,6,6-trimethylcyclohexen-1-yl)but-3-en-2-one

PubChem CID 97996 ↗

References

  1. 1ISO 16128-1:2016 and ISO 16128-2:2017 — Guidelines on technical definitions and criteria for natural and organic cosmetic ingredients and products. ISO, Geneva.
  2. 2Methyl Ionones. PubChem CID 97996. National Center for Biotechnology Information. pubchem.ncbi.nlm.nih.gov ↗
  3. 3METHYL IONONES. CosIng — European Commission cosmetic ingredient database. ec.europa.eu/cosing ↗
  4. 4METHYL IONONES. CosIng u2014 European Commission database for information on cosmetic substances and ingredients. https://ec.europa.eu/growth/tools-databases/cosing/search?search=METHYL%20IONONES