Database/Perfuming/Geranyl Butyrate
Route-dependent · ISO 16128

Is Geranyl Butyrate natural?

It depends. Geraniol is natural origin from essential oils or pine-turpentine myrcene and petrochemical from isobutylene-based citral; butyric acid is natural from fermentation and petrochemical from the oxo process.

INCI nameGeranyl Butyrate
CAS106-29-6
FormulaC14H24O2 · 224.34 Da
FunctionPerfuming
FeedstockMost geranyl butyrate is geraniol esterified with oxo-process…

Why the score varies

This ingredient is made commercially by more than one route, and ISO 16128 scores the feedstock actually used. Without a supplier certificate of origin the value cannot be claimed.

RouteFeedstockNOIShareNotes
Natural essential-oil isolateGeraniol fractionated from citronella/palmarosa oil, esterified with fermentation-derived butyric acid1.00~20%
Pine-derived geraniol + petrochemical butyric acidgeraniol made from pine-turpentine myrcene, esterified with oxo-process butyric acid0.68large sharegeranyl 153.25 Da natural of 224.34 Da
Petrochemical geraniol + petrochemical butyric acidgeraniol from isobutylene-based citral, esterified with oxo-process butyric acid0.00large share
Ask your supplier. A batch-specific certificate of origin or bio-based carbon test (ASTM D6866) settles which route applies.

How we scored it

Geranyl part C10H17O 153.25 Da + butyryl C4H7O 71.10 Da = 224.34 Da. Natural geraniol and fermentation butyric acid: 1.00. Pine-derived geraniol with petrochemical butyric acid: 153.25/224.34 = 0.68. Isobutylene-based geraniol: 0.00.
What counts. ISO 16128-2 scores the atoms that remain in the final ingredient. Reagents, solvents, catalysts and protecting groups used during manufacture leave no mass behind and are not counted.

Where it comes from

Most geranyl butyrate is geraniol esterified with oxo-process butyric acid; the geraniol is made from pine-turpentine myrcene (natural origin) or from isobutylene-based citral (petrochemical). A minority uses essential-oil geraniol with fermentation butyric acid.

In plain English

A fruity, sweet-smelling fragrance ingredient. It joins geraniol, from flower oils or pine terpenes or petrochemicals, to butyric acid, from fermentation or petrochemicals, so its natural content depends on the supplier.

Natural alternatives with the same function

Structure

2D structure of Geranyl Butyrate

[(2E)-3,7-dimethylocta-2,6-dienyl] butanoate

PubChem CID 5355856 ↗

References

  1. 1ISO 16128-1:2016 and ISO 16128-2:2017 — Guidelines on technical definitions and criteria for natural and organic cosmetic ingredients and products. ISO, Geneva.
  2. 2Geranyl Butyrate. PubChem CID 5355856. National Center for Biotechnology Information. pubchem.ncbi.nlm.nih.gov ↗
  3. 3GERANYL BUTYRATE. CosIng — European Commission cosmetic ingredient database. ec.europa.eu/cosing ↗
  4. 4GERANYL BUTYRATE. CosIng u2014 European Commission database for information on cosmetic substances and ingredients. https://ec.europa.eu/growth/tools-databases/cosing/search?search=GERANYL%20BUTYRATE