Database/Fragrance/Triethyl Citrate
100% natural origin · ISO 16128

Is Triethyl Citrate natural?

Yes. Citric acid is a fermentation product; ethanol is assumed bioethanol (fermentation), the dominant global feedstock for esterification-grade ethanol.

INCI nameTriethyl Citrate
CAS77-93-0
FormulaC12H20O7 · 276.28 Da
FunctionFragrance · Plasticiser
FeedstockMade by esterifying fermentation-derived citric acid with ethanol,…

How we scored it

Citric acid core C6H5O7 192 Da (fermentation, natural) + 3 ethyl groups from bioethanol (assumed dominant route, natural) = 276/276 → 1.0
What counts. ISO 16128-2 scores the atoms that remain in the final ingredient. Reagents, solvents, catalysts and protecting groups used during manufacture leave no mass behind and are not counted.

How it’s made

Fischer esterification of citric acid with ethanol (first arm drawn). The film draws the key step and names the steps after it. Each curved arrow moves one electron pair, and the film ends on the score above.

Where it comes from

Made by esterifying fermentation-derived citric acid with ethanol, assumed to be bioethanol (fermentation of corn/sugarcane), the dominant commercial source. A petrochemical (ethylene-derived) ethanol route also exists and would lower the value to about 0.70.

In plain English

An ester made from citric acid (from fermented sugars) and ethanol. Used as a solvent, plasticizer, and fragrance ingredient, and to help control how formulas flow.

CosIng definition: Triethyl Citrate is the triester of ethyl alcohol and citric acid that conforms to the formula

Structure

2D structure of Triethyl Citrate

triethyl 2-hydroxypropane-1,2,3-tricarboxylate

PubChem CID 6506 ↗

References

  1. 1ISO 16128-1:2016 and ISO 16128-2:2017 — Guidelines on technical definitions and criteria for natural and organic cosmetic ingredients and products. ISO, Geneva.
  2. 2Triethyl Citrate. PubChem CID 6506. National Center for Biotechnology Information. pubchem.ncbi.nlm.nih.gov ↗
  3. 3TRIETHYL CITRATE. CosIng — European Commission cosmetic ingredient database. ec.europa.eu/cosing ↗
  4. 4TRIETHYL CITRATE. CosIng u2014 European Commission database for information on cosmetic substances and ingredients. https://ec.europa.eu/growth/tools-databases/cosing/search?search=TRIETHYL%20CITRATE