Database/Emollient/Octyldodecyl Ethylhexanoate
Route-dependent · ISO 16128

Is Octyldodecyl Ethylhexanoate natural?

It depends. Octyldodecanol is a Guerbet alcohol made from decanol that is either coconut/palm-kernel derived or petrochemical, while 2-ethylhexanoic acid is always petrochemical, capping the natural route at 0.70.

INCI nameOctyldodecyl Ethylhexanoate
CAS69275-04-3
FunctionEmollient
FeedstockHeadlined route: Guerbet condensation of plant-derived decanol from…

Why the score varies

This ingredient is made commercially by more than one route, and ISO 16128 scores the feedstock actually used. Without a supplier certificate of origin the value cannot be claimed.

RouteFeedstockNOIShareNotes
Plant-derived Guerbet decanolCoconut or palm-kernel decanol condensed to octyldodecanol; 2-ethylhexanoic acid petrochemical0.70~50%
Petrochemical Guerbet decanolZiegler or oxo decanol from ethylene or propylene; 2-ethylhexanoic acid petrochemical0.00~50%
Ask your supplier. A batch-specific certificate of origin or bio-based carbon test (ASTM D6866) settles which route applies.

How we scored it

Plant route: octyldodecyl-O C20H41O 297.5 natural; 2-ethylhexanoyl C8H15O 127.2 petrochemical; 297.5/424.8 = 0.70. Petrochemical Ziegler/oxo decanol route: 0/424.8 = 0.00.
What counts. ISO 16128-2 scores the atoms that remain in the final ingredient. Reagents, solvents, catalysts and protecting groups used during manufacture leave no mass behind and are not counted.

Where it comes from

Headlined route: Guerbet condensation of plant-derived decanol from coconut or palm-kernel oil to octyldodecanol, esterified with propylene-derived 2-ethylhexanoic acid. Alternative: decanol from Ziegler ethylene growth or oxo chemistry gives an entirely petrochemical ester, and the two routes supply roughly similar volumes.

In plain English

A smooth emollient ester that softens skin and gives products a spreadable feel. It combines octyldodecanol, a branched alcohol that can be plant-derived or petrochemical, with 2-ethylhexanoic acid, which is petrochemical.

Natural alternatives with the same function

References

  1. 1ISO 16128-1:2016 and ISO 16128-2:2017 — Guidelines on technical definitions and criteria for natural and organic cosmetic ingredients and products. ISO, Geneva.
  2. 2OCTYLDODECYL ETHYLHEXANOATE. CosIng — European Commission cosmetic ingredient database. ec.europa.eu/cosing ↗
  3. 3OCTYLDODECYL ETHYLHEXANOATE. CosIng u2014 European Commission database for information on cosmetic substances and ingredients. https://ec.europa.eu/growth/tools-databases/cosing/search?search=OCTYLDODECYL%20ETHYLHEXANOATE